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Scientific Projects

Below are brief summaries of my major research projects. A complete list of all publications can be found via the links above. Please CONTACT ME for additional information or to discuss collaborations!

Epistemic Metacognition

post-doc research

advisor: Milo Koretsky

We investigate the reactions of 267 students across 6 diverse institutions to a conceptual statics question. Across institutions, there is no difference in student correctness, but a significant difference in whether students feel that the question made them think deeply about course material. We conclude that even when instructors prepare their students equally well to answer questions correctly, they may yet instill very different ideas about what learning means, thus affecting their students' epistemic metacognition. 

Publications:

I had to be able to think deeper about the meaning behind the concepts rather than just using numbers to calculate a value

there is no math involved so it's not really asking vital material

Annealing and Conductivity

Ph.D. research

advisor: Nitash Balsara

There are conflicting reports in the literature as to the effect of annealing on ionic conductivity in block copolymer electrolytes. By monitoring grain size and ionic conductivity in a series of block copolymer electrolytes, we find that the relationship between ionic conductivity and grain size depends on salt concentration, initial grain size, and the nature of the defects between grains.

Publications:

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Solubility Limit(s) of LiTFSI in PEO

Ph.D. research

advisor: Nitash Balsara

The limiting current can be reached when the salt concentration in a cell reaches its solubility limit, and therefore cannot increase further. We find the solubility limit in PEO / LiTFSI electrolytes to be r = 0.50. However, we also find two-phase coexistence between r = 0.28 and r = 0.50. Concentrated solution theory was developed to characterize single-phase electrolytes, and therefore cannot be applied to PEO / LiTFSI electrolytes when the salt concentration at any position in the cell exceeds r = 0.28.

Publications:

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in situ X-ray Scattering

Ph.D. research

advisor: Nitash Balsara

Using small-angle X-ray scattering (SAXS) during in situ cycling of an electrochemical cell, we observed orientation-dependent grain swelling and contraction, which may impact the steepest-accessible concentration gradients and therefore the highest-accessible current density in the cell, or the limiting current. In a different study, we observe that equilibrium morphological transitions are not always accessible during polarization, which provides a new mechanism for the limiting current.

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Selected Presentations:

Implications of
Frictional Interactions

Ph.D. research

advisor: Nitash Balsara

Combining pulsed-field gradient (PFG) NMR, electrochemical and viscometry measurements, and theory, I determined that in some systems, cation-anion interactions determine conductivity even in the dilute limit, challenging prominent assumptions in the field.

Selected Presentations:

  • APS March Meeting 2021

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Magnetic Field Alignment

Ph.D. research

advisor: Nitash Balsara

I discovered that ordered block copolymer electrolytes can be oriented through exposure to strong magnetic fields, and that the NMR signature of this alignment can be used to detect order-to-disorder transitions.

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Selected Presentations:

  • APS March Meeting 2019

  • ACS Fall Meeting 2020, invited

Polymer Nanoparticle Morphologies

undergraduate research

advisor: Prof. Rodney Priestley

I independently tuned molecular weight and composition of block copolymer and block copolymer / homopolymer blend nanoparticles, using OsO4 staining and electron microscopy to observe never-before-reported morphologies

Publications:

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